Antiferromagnet–ferromagnet transition in the cobaltites

Магнетизм

Анотація

The three series oxygen-deficient cobaltites La_0.5Ba_0.5CoO_3–δ, LnBaCo₂O_5.5 and Sr₂YCo₄O_10.5 have been studied. It has been shown that La_0.5Ba_0.5CoO₃ is an insulating ferromagnet whereas La_0.5Ba_0.5CoO_2.75 is a pure antiferromagnet in which the oxygen vacancies are disordered. The oxygen-vacancies ordering leads to appearance of the ferromagnetic component apparently due to a formation of the noncollinear magnetic structure. The antiferromagnet–“ferromagnet” transition is accompanied by a giant magnetoresistance. It is suggested that in the ferromagnetic oxidized compounds Co³⁺ and Co⁴⁺ ions adopt intermediate spin state whereas for antiferromagnetic (Co⁴⁺-free) compositions Co³⁺ ions have high-spin state (pyramids CoO₅) and dominant low-spin state (octahedra CoO₆). In both ferromagnetic and antiferromagnetic compounds the superexchange via oxygen plays an essential role in a formation of the magnetic properties.