Cathodoluminescence characterization of polystyrene–BaZrO3 hybrid composites

Автор(и)

  • V.P. Savchyn Ivan Franko National University of Lviv, Ukraine
  • A.I. Popov Institute of Solid State Physics, University of Latvia, Riga, Latvia
  • O.I. Aksimentyeva Ivan Franko National University of Lviv, Ukraine
  • H. Klym Lviv Polytechnic National University, Ukraine
  • Yu.Yu. Horbenko Ivan Franko National University of Lviv, Ukraine
  • V. Serga Institute of Inorganic Chemistry, Riga Technical University, Latvia
  • A. Moskina Institute of Solid State Physics, University of Latvia, Riga, Latvia
  • I. Karbovnyk Ivan Franko National University of Lviv, Ukraine

DOI:

https://doi.org/10.1063/1.4959020%20

Ключові слова:

BaZrO3 powders, cathodoluminescence spectroscopy, hybrid composite, polystyrene.

Анотація

The radiation properties and the electronic structure of hybrid composites based on suspension polystyrene (PS) and nanocrystals of BaZrO3 (BZO) (d < 50 nm) have been studied using luminescent spectroscopy and x-ray analysis. A strong cathodoluminescence (CL) in BZO-nanocrystals is observed in temperature range 80–293 K. It is modified in BZO–PS composites: both the low- and a high-energy bands (near 4 eV) appear, to-gether with a significant reduction in the CL intensity. A decrease of the lattice parameter а for BZO phase in the composite and the modification of CL spectra indicate for changes in the nanocrystalline structure induced by the polymer.

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Опубліковано

2016-05-18

Як цитувати

(1)
Savchyn, V.; Popov, A.; Aksimentyeva, O.; Klym, H.; Horbenko, Y.; Serga, V.; Moskina, A.; Karbovnyk, I. Cathodoluminescence Characterization of polystyrene–BaZrO3 Hybrid Composites. Fiz. Nizk. Temp. 2016, 42, 760-763.

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