Orientational order parameter in CO2-based alloys with rare gases from THEED data: pure CO2

Classical Cryocrystals

Автор(и)

  • V.V. Danchuk B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine 47 Lenin Ave., Kharkov 61103, Ukraine
  • A.A. Solodovnik B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine 47 Lenin Ave., Kharkov 61103, Ukraine
  • M.A. Strzhemechny B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine 47 Lenin Ave., Kharkov 61103, Ukraine

DOI:

https://doi.org/10.1063/1.2755200

Ключові слова:

electron diffraction, rare gases alloys, orientational order.

Анотація

Using the transmission high-energy electron diffraction technique, we studied the temperature dependence of the diffraction reflection intensities from the solid phase of CO2. To deduce absolute values of the orientational order parameter, we modified the existing reconstruction method to account for the triatomic shape of the molecule. It is shown that for triatomics solids a higher-rank order parameter, n4, is important and cannot be neglected. Application of the modified approach yielded n, and n4, values as a function of temperature over the range from 6 to 70 K. Both orientational order parameters proved to be a nonmonotone function of temperature.

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Опубліковано

2007-05-30

Як цитувати

(1)
Danchuk, V.; Solodovnik, A.; Strzhemechny, M. Orientational Order Parameter in CO2-Based Alloys With Rare Gases from THEED Data: Pure CO2: Classical Cryocrystals. Fiz. Nizk. Temp. 2007, 33, 783-789.

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