The influence of temperature and pressure on the thermodynamic coefficient –∂V/∂PT for water and argon

Автор(и)

  • L. A. Bulavin Department of Molecular Physics, Faculty of Physics, Taras Shevchenko National University of Kyiv, Kyiv 03127 Ukraine
    Institute for Safety Problems of Nuclear Power Plants, National Academy of Sciences of Ukraine, Kyiv 03028 Ukraine     https://orcid.org/0000-0002-8063-6441
  • O. I. Bilous Computational and Soft Matter Physics, Faculty of Physics, University of Vienna, 1090 Vienna, Austria https://orcid.org/0000-0001-9071-0169
  • Yu. L. Zabulonov Institute of Environmental Geochemistry, National Academy of Sciences of Ukraine, Kyiv 03142, Ukraine
  • Ye. G. Rudnikov Department of Molecular Physics, Faculty of Physics, Taras Shevchenko National University of Kyiv, Kyiv 03127 Ukraine
    Department of Biomedical Cybernetics, Faculty of Biomedical Engineering, National Technical Universityof Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv 03056, Ukraine     https://orcid.org/0000-0002-6328-1650
  • N. I. Lebovka F. D. Ovcharenko Institute of Biocolloidal Chemistry, National Academy of Sciences of Ukraine, Kyiv 03142 Ukraine https://orcid.org/0000-0002-8314-0601

DOI (Low Temperature Physics):


https://doi.org/10.1063/10.0046489

Ключові слова:

water, argon, isothermal compressibility, liquid–vapor coexistence curve, liquid–solid coexistence curve, hydrogen bonds

Анотація

Досліджено вплив температури T та тиску P на термодинамічний коефіцієнт –(∂V/∂P)T рідкої води та аргону. На основі принципу відповідних станів було підтверджено існування області термодинамічної подібності між цими речовинами. Однак за певних термодинамічних умов ця аналогія порушується, і вода демонструє відмінну поведінку щодо термодинамічного коефіцієнта –(∂V/∂P)T. Зокрема, для води було визначено характерну температуру Tc = (42,2 ± 0,20) °C, за якої температурна залежність –(∂V/∂P)T демонструє виражений мінімум на перетині з межею рівноваги рідина–пара. Крім того, мінімуми в температурній залежності цього коефіцієнта вздовж ізобар спостерігаються для води за температури вище Tc. Також криві залежності –(∂V/∂P)T від тиску перетинаються попарно вздовж ізотерм при температурах нижче цього значення. Навпаки, аргон не демонструє таких температурно-баричних особливостей у відповідному термодинамічному коефіцієнті.

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Опубліковано

2026-08-23

Як цитувати

(1)
L. A. Bulavin, O. I. Bilous, Yu. L. Zabulonov, Ye. G. Rudnikov, and N. I. Lebovka, The influence of temperature and pressure on the thermodynamic coefficient –∂V/∂PT for water and argon, Low Temp. Phys. 52, 1159–1165, (2026) [Fiz. Nyzk. Temp. 52, 1284–1290, (2026)] DOI: https://doi.org/10.1063/10.0046489.

Номер

Том 52 № 10 (2026)

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Квантові рідини та квантові кристали

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